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They traveled over the wretched roads or waterways in armed bands, which became fraires, compagnies, gilds, or hanses These wanderers sought the protection of the new burgs ; outside them they built faubourgs, portuses, places of transit They frequented London and Champagne Their economic significance was as yet slight, for trade was small, but their future development revolutionized the European economy It was in this century that Venice obtained decisive concessions from the Emperor at Constantinople: freedom from customs and the establishment of a Venetian factory and colony on the Bosphorus In Venice serfdom was unknown Almost the entire population engaged in maritime trade There was continuous trouble with the pirates of the Adriatic, but relations were extended to Pavia, Ravenna, and many coastal ports In spite of opposition from the Papacy, Venice also developed its trade with the Moslem world.

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Aug 2, 2018 · This PNG image is then pasted onto the empty PDF at the coordinates (0,0) , resized at (211,298) (line 6). A4 format is 210 mm wide, and 297 ...

, 1988] For example, f for AIBN in the polymerization of styrene decreases from 075 at conversions up to 30% to 020 at 90 95% conversion [Solomon and Moad, 1987] In some cases f varies with solvent as a result of the solvent reacting with radicals before the radicals can initiate polymerization The initiator ef ciencies of AIBN, benzoyl peroxide, and t-butyl hydroperoxide are lower in carbon tetrachloride or 1-chlorooctane than in aromatic solvents [Nozaki and Bartlett, 1946; Shahani and Indictor, 1978; Walling, 1954] Reactions of radicals with solvents are discussed further in Sec 3-6 The change in initiator ef ciency with solvent may in a few instances be due to a solvation effect, for example, the speci c solvation of electrophilic radicals by electron-donor solvents [Martin, 1973] The initiator ef ciency for any particular initiator may also vary for different monomers.

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Thus the value of f for AIBN in the polymerizations of methyl methacrylate, vinyl acetate, styrene, vinyl chloride, and acrylonitrile ranged from 06 to 10, increasing in that order [Arnett and Peterson, 1952] This order is a consequence of the relative rates with which radicals add to the different monomers 3-4g-3 Experimental Determination of f.

Venetians began investing money in maritime ventures on a scale requiring some financial organization Coiners and money changers rose steadily in power and prestige, and commercial.

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Various methods are employed for the experimental evaluation of the initiator ef ciency. (These methods are generally also applicable to determining f for photopolymerization). One method involves the determination and comparison of both the initiator decomposition and the production of polymer molecules. The initiator decomposition is best determined during an actual polymerization. Independent measurement of initiator decomposition in the absence of monomer can give erroneous results. The rates of decomposition of initiator can be quite different for pure initiator as compared to initiator in the presence of monomer, since f varies with monomer concentration. Also in some cases monomer is involved in the initiation step [e.g., molecule-induced homolysis (Eq. 3-35), certain redox initiations described in Sec. 3-4b-1]. AIBN decomposition can be followed relatively easily by following the evolution of nitrogen. Measurement of the polymer number-average molecular weight allows a determination of f by comparison of the number of radicals produced with the number of polymer molecules obtained. This method requires a knowledge of whether termination occurs by coupling or disproportionation, since the former results in two initiator fragments per polymer molecule and the latter in only one. The occurrence of induced decomposition must be taken into account in calculating the number of radicals produced. Induced decomposition is negligible for azonitriles but occurs to an appreciable extent with many peroxides. The second method is a variation of the rst in which the number of initiator fragments in the polymer is determined by direct analysis of the polymer end groups. The analysis is relatively dif cult to perform accurately because of the low concentration of the end groups. For a 50,000-molecular-weight polymer, the end groups constitute only $0.1% of the total

independent of whether the other functional groups in the monomer have reacted. Neither of these assumptions is valid for 2,4-tolylene diisocyanate (IV)

which is one of diisocyanate monomers used in the synthesis of polyurethanes [Caraculacu and Coseri, 2001]. Urethane formation can be depicted as occurring by the sequence

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